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Polymer Editing Upcycles Waste Into Higher-Performance Plastics

Two metathesis processes could improve plastic waste’s effects on the environment and circular economy

To upcycle the polymers of discarded plastics, chemists at Oak Ridge National Laboratory invented a way to generate new macromolecules with more valuable properties than those of the starting material. Credit: Adam Malin/ORNL, U.S. Department of Energy

Oak Ridge National Laboratory
Wed, 03/05/2025 - 12:01
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By editing the polymers of discarded plastics, chemists at the U.S. Department of Energy’s Oak Ridge National Laboratory (ORNL) have found a way to generate new macromolecules with more valuable properties than those of the starting material. Upcycling may help remedy the roughly 450 million tons of plastic discarded worldwide annually, of which only 9% gets recycled; the rest is incinerated or winds up in landfills, oceans, or elsewhere.

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ORNL’s invention may change plastic’s environmental fate by rearranging polymeric building blocks to customize the properties of plastics. Molecular subunits link to produce polymer chains that can connect through their backbones and cross-linked molecules to form multipurpose plastics. The makeup of polymer chains determines how strong, rigid, or heat-resistant those plastics will be.

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